ST_ScaleX — Returns the X component of the pixel width in units of coordinate reference system.
float8 ST_ScaleX(raster  rast);
Returns the X component of the pixel width in units of coordinate reference system. Refer to World File for more details.
Changed: 2.0.0. In WKTRaster versions this was called ST_PixelSizeX.
SELECT rid, ST_ScaleX(rast) As rastpixwidth
FROM dummy_rast;
 rid | rastpixwidth
-----+--------------
   1 |            2
   2 |         0.05