~= — Returns TRUE if A's bounding box is the same as B's.
boolean ~=(
                  raster 
                  A
                , 
                  raster 
                  B
                );
The ~= operator returns TRUE if the bounding box of raster A
        is the same as the bounding box of raster B.
                 
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                 This operand will make use of any indexes that may be available on the rasters.  | 
            
Availability: 2.0.0
Very useful usecase is for taking two sets of single band rasters that are of the same chunk but represent different themes and creating a multi-band raster
SELECT ST_AddBand(prec.rast, alt.rast) As new_rast
    FROM prec INNER JOIN alt ON (prec.rast ~= alt.rast);