ST_PixelAsPoints — Returns a point geometry for each pixel of a raster band along with the value, the X and the Y raster coordinates of each pixel. The coordinates of the point geometry are of the pixel's upper-left corner.
setof record ST_PixelAsPoints(raster  rast, integer  band=1, boolean  exclude_nodata_value=TRUE);
Returns a point geometry for each pixel of a raster band along with the value, the X and the Y raster coordinates of each pixel. The coordinates of the point geometry are of the pixel's upper-left corner.
                    Return record format: geom geometry, val double precision, x integer, y integers.
                
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                        When   | 
Availability: 2.1.0
Changed: 2.1.1 Changed behavior of exclude_nodata_value.
SELECT x, y, val, ST_AsText(geom) FROM (SELECT (ST_PixelAsPoints(rast, 1)).* FROM dummy_rast WHERE rid = 2) foo;
 x | y | val |          st_astext
---+---+-----+------------------------------
 1 | 1 | 253 | POINT(3427927.75 5793244)
 2 | 1 | 254 | POINT(3427927.8 5793244)
 3 | 1 | 253 | POINT(3427927.85 5793244)
 4 | 1 | 254 | POINT(3427927.9 5793244)
 5 | 1 | 254 | POINT(3427927.95 5793244)
 1 | 2 | 253 | POINT(3427927.75 5793243.95)
 2 | 2 | 254 | POINT(3427927.8 5793243.95)
 3 | 2 | 254 | POINT(3427927.85 5793243.95)
 4 | 2 | 253 | POINT(3427927.9 5793243.95)
 5 | 2 | 249 | POINT(3427927.95 5793243.95)
 1 | 3 | 250 | POINT(3427927.75 5793243.9)
 2 | 3 | 254 | POINT(3427927.8 5793243.9)
 3 | 3 | 254 | POINT(3427927.85 5793243.9)
 4 | 3 | 252 | POINT(3427927.9 5793243.9)
 5 | 3 | 249 | POINT(3427927.95 5793243.9)
 1 | 4 | 251 | POINT(3427927.75 5793243.85)
 2 | 4 | 253 | POINT(3427927.8 5793243.85)
 3 | 4 | 254 | POINT(3427927.85 5793243.85)
 4 | 4 | 254 | POINT(3427927.9 5793243.85)
 5 | 4 | 253 | POINT(3427927.95 5793243.85)
 1 | 5 | 252 | POINT(3427927.75 5793243.8)
 2 | 5 | 250 | POINT(3427927.8 5793243.8)
 3 | 5 | 254 | POINT(3427927.85 5793243.8)
 4 | 5 | 254 | POINT(3427927.9 5793243.8)
 5 | 5 | 254 | POINT(3427927.95 5793243.8)